Accuracy in powder diffraction

proceedings of a Symposium on Accuracy in Powder Diffraction held at the National Bureau of Standards, Gaithersburg, Maryland, June, 11-15, 1979 by Symposium on Accuracy in Powder Diffraction (1979 National Bureau of Standards)

Publisher: U.S. Dept. of Commerce, National Bureau of Standards : for sale by the Supt. of Docs., U.S. Govt. Print. Off. in [Washington, D.C.]

Written in English
Published: Pages: 572 Downloads: 342
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Subjects:

  • X-rays -- Diffraction -- Measurement -- Congresses.,
  • Powders -- Optical properties -- Measurement -- Congresses.,
  • Chemistry, Physical and theoretical -- Congresses.

Edition Notes

Statementedited by S. Block, C. R. Hubbard ; sponsored by International Union of Crystallography [and] Chemistry Division, National Research Council of Canada [and] National Measurement Laboratory, National Bureau of Standards.
SeriesNBS special publication ; 567, NBS special publication ;, 567.
ContributionsBlock, Stanley, 1926-, Hubbard, C. R., International Union of Crystallography., National Research Council of Canada. Division of Chemistry (1969/70- ), National Measurement Laboratory (U.S.)
Classifications
LC ClassificationsQC100 .U57 no. 567, QC482.D5 .U57 no. 567
The Physical Object
Paginationx, 572 p. :
Number of Pages572
ID Numbers
Open LibraryOL4235987M
LC Control Number80600010

  The Interpretation of Powder Diffraction Data. The Viewing and Precision Measurement of Powder Photographs. Determination of Interplanar (d) Spacings. Debye-Scherrer Patterns, Monochromatic-Pinhole (Flat-Film) Patterns, Indexing Cubic Powder Patterns. Reciprocal-Lattice Picture of Diffraction by a Cubic Cited by: X-ray crystallography (XRC) is the experimental science determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to diffract into many specific directions. By measuring the angles and intensities of these diffracted beams, a crystallographer can produce a three-dimensional picture of the density of electrons within the. Defect and Microstructure Analysis by Diffraction looks at a key aspect of state-of-the-art methods for analyzing the actual structure of materials. Diffraction analysis is typically based on idealized crystals. The impurities and irregularities that work themselves into virtually all crystal structures, however, cause diffraction peak profiles to broaden and sometimes become asymmetric 5/5(2). The powder diffraction pattern of Ba3(P3O9)24H2O is plotted in Figure 1(a), and the powder diffraction data for the compound are reported in Table I. BaNH4P3O92H2O is monoclinic, space group P21/n, Z = 4, with a = (1), b = (1), c = (1) Å, β = (1)°, V = (3) Å3, M(20) = 9 ( = 9), and F(

Hull appeared in the book celebrating 50 years of x-ray diflkction which was edited by P.P. Ewald and published by the International Union for Crystallography in The Powder Diffraction File The application of x-ray powder diffraction patterns to the identification and analysis of materials initially developed locally in many laboratories. For polycrystalline samples high resolution powder diffraction measurements generally will provide adequate accuracy for stress evaluation. For textured (oriented) and single crystalline materials, 4-circle diffractometry is needed in which the sample is rotated so that measurements on multiple diffraction peaks can be carried out. X-ray powder diffraction is best known for phase analysis (Hanawalt files) dating back to the 30s. In the late 60s the inherent potential of powder diffraction for crystallographic problems was realized and scientists developed methods for using powder diffraction . Neutron powder diffractometers nowadays incorporate multiple detectors. This chapter begins with the data reduction to present a single record of intensity against angle (for CW diffractometers) or time-of-flight. The importance of visual inspection to assess peak resolution, peak shapes, noise, and background is stressed. Subsequent analyses such as phase identification via a search/match.

THE PRINCIPLES OF X-RAY DIFFRACTION 83 Now the difference of optical path for the top and bottom wave is shown by the heavy-drawn path lying between two parts of the wave-fronts of the incident and reflected waves. Its length is 2Nd sin 0. The path difference between reflections on File Size: 1MB. The primary results desired are accurate and precise (i.e. reproducible) intensities, and minimizing systematic sample-related effects is probably more important than accounting for instrumental systematic errors in the collection of accurate and precise diffraction data. X-ray powder diffraction has at its heart two primary assumptions, namely. POWDER DIFFRACTION ANALYSIS OF HYDRAULIC CEMENTS: ASTM RIETVELD ROUND ROBIN RESULTS ON PRECISION Paul Stutzman Building and Fire Research Laboratory, National Institute of Standards and Technology ABSTRACT Phase composition estimates by X-ray powder diffraction and Rietveld analysis are becoming more widely used in the cement industry.   Whitfield PS, Le Page Y, Davidson IJ () Ab initio structure determination of the low temperature phase of succinonitrile from X-ray powder diffraction data – coping with potential poor quality using DFT ab initio methods. Powder Diffr – ADS CrossRef Google ScholarAuthor: L’ubomír Smrčok.

Accuracy in powder diffraction by Symposium on Accuracy in Powder Diffraction (1979 National Bureau of Standards) Download PDF EPUB FB2

Powder Diffraction notes for authors. SCOPE. Powder Diffraction is a quarterly journal publishing articles, both experimental and theoretical, on the use of powder diffraction and related techniques for the characterization of crystalline is published by Cambridge University Press (CUP) for the International Centre for Diffraction Data (ICDD).

Accuracy In Powder Diffraction. Proceedings of a Symposium on Accuracy in Powder Diffraction Held at the National Bureau of Standards, Gaithersburg, Maryland, June(NBS Special Publicati [Block, S. & C.R.

Hubbard, eds.] on *FREE* shipping on qualifying offers. Accuracy In Powder Diffraction. Proceedings of a Symposium on Accuracy in Powder Diffraction Held at the Author: eds. Block, S. & C.R. Hubbard. in powder diffraction surely deserve to be ranked as another such milestone.

The first conference on Accuracy in Powder Diffraction organized in by the National Institute of Standards and Technology (NIST) (formerly the National Bureau of Standards) was a harbinger of this coming development.

The. Powder diffraction is a scientific technique using X-ray, neutron, or electron diffraction on powder or microcrystalline Accuracy in powder diffraction book for structural characterization of materials.

An instrument dedicated to performing such powder measurements is called a powder diffractometer. Powder diffraction stands in contrast to single crystal diffraction techniques, which work best with a single, well. Get this from a library. Accuracy in powder diffraction II: proceedings of the international conference, May[Edward Prince; J K Stalick; International Union of Crystallography.

Commission on Powder Diffraction.; JCPDS--International Centre for Diffraction Data.; National Institute of Standards and Technology (U.S.);]. Mineral powder diffraction file: search manual: chemical name, hanawalt, fink, mineral name by International Centre for Diffraction Data (Book) 7 editions published between and in English and held by 62 WorldCat member libraries worldwide.

Full text of "Accuracy in powder diffraction II" See other formats. @article{osti_, title = {Accuracy in quantitative x-ray powder diffraction analyses}, author = {Bish, D J and Chipera, S J}, abstractNote = {Accuracy, or how well a measurement conforms to the true value of a parameter, is important in XRD analyses in three primary areas, (1) 2{theta} position or d-spacing; (2) peak shape; and (3) intensity.

Book Review - Introduction to X-Ray Powder Diffraction, Ron Jenkins and Robert L. Snyder, John Wiley and Sons, Inc, ISBN+ xxiii pp. This banner text can have markup. web; books; video; audio; software; images; Toggle navigation. One of these methods, X-ray powder diffraction (XRD), is an instrumental technique that is used to identify minerals, as well as other crystalline materials.

In many geologic investigations, XRD complements other mineralogical methods, including optical light microscopy, electron microprobe microscopy, and scanning electron microscopy.

The accuracy of laser diffraction size measurements of dry powder inhaler particles, which play an important role in guiding effective inhaler system design, is assessed.

X-ray powder diffraction (XRPD) techniques are used to characterize samples in the form of loose powders, aggregates of finely divided material or polycrystalline specimens. This article provides a detailed account of XRPD. It begins with a discussion on XRPD instrumentation and the techniques used to characterize samples.

At the Denver X-Ray Conference, the topic for the plenary lectures alternates annually between x-ray diffraction and x-ray fluorescence. This year is a "diffraction" year, and the theme is accuracy in powder diffraction. Instead of comprehensive cover­ age, such as was attempted at the Accuracy inBrand: Springer US.

Accuracy In X-ray Powder Diffraction: A Comparison of Quantitative Methods 21 Nicola V.Y. Scarlett and Ian C. Madsen Internet Available Rietveld Software 24 Lachlan M. Cranswick Dealing with unknown impurity phases 30 W.I.F.

David Rietveld refinements with JANA 32 Michal Dušek, Václav Petricek, Markus Wunschel. The X-ray diffraction analysis showed that the pentanary compound CuZnInCrSe4 crystallizes in the monoclinic structure with lattice parameters a = ( ± ) Å, b = ( ± ) Å.

Effect of planar defects in crystals on the position of powder diffraction lines, A. Ustinov Effect of stacking disorder on the profile of the powder diffraction line, Z. Weiss and P. Capkova Part II. Experimental techniques Crystallite statistics and accuracy in powder diffraction intensity measurements, Deane K.

Smith X-ray powder diffraction is a fast technique to identify the crystalline structure of the nanomaterial as well as to identify the unit cell structure and atomic spacing [–].Coincidence of monochromatic X-rays which are produced from cathode ray tube and the specific crystalline sample plays a major role in determining the crystal structure.

X-ray powder patterns of natural graphite and coke heat-treated at °C are shown in Fig. For X-ray powder pattern of the coke having turbostratic structure, it is characteristically observed that 10 and 11 diffraction profiles are asymmetric and broad, as compared with symmetrical and sharp and diffraction profiles of natural graphite, as well as broadening of 00l diffraction Cited by: Powder diffraction is complementary to the book's main technique of single-crystal diffraction; it can provide a check on purity and homogeneity of samples, and may be the only possible approach for some materials.

The two methods are compared. The main limitation in powder diffraction is the one-dimensional nature of the data. Many variants are possible for the basic powder diffraction.

The Powder Diffraction File: Past, Present, and Future Volume Number 3 May–June Deane K. Smith and Ron Jenkins JCPDS-International Centre for Diffraction Data, Newtown Square, PA The Powder Diffraction file has been the primary reference for Powder Diffraction Data for more than half a century.

The file is a collection of about File Size: KB. Advanced Methods in X-ray Powder Diffraction, is designed for the experienced user and focuses on computer-based methods of qualitative and quantitative phase analysis, as well as crystal structure analysis and refinement.

For maximum benefit from the Advanced Methods in X-ray Powder Diffraction, the ICDD Clinic faculty strongly recommends that. X-ray powder diffraction data of hauyne with incommensurate modulated structure from volcanic rocks of Laacher Lake, Germany (3) Kevin R. Henke, Jeffrey C. Bryan, and Mark P.

Elless Structure and powder diffraction pattern of 2,4,6-Trimercapto-s-triazine, trisodium salt (Na 3 S 3 C 3 N 3 9H 2 O) (7). Electron microscopes are usually supplied with equipment for obtaining diffraction patterns and micrographs from the same area of a specimen and the best results are attained if the complete use is to be made of these combined facilities.

Electron diffraction patterns are used to obtain quantitative data including phase identification, orientation relationship and crystal defects in materials. An accurate quantitative mineral analysis requires: (1) proper interpetation of both whole-rock and clay-fraction X-ray powder diffraction (XRD) data to identify all phases present, and (2) application of several measured sample properties (e.g., chemistry) to define mineral proportions.

The use of X-ray powder diffraction as a method for air monitoring was discussed. Most of the airborne dusts monitored by this method have been crystalline compounds, which indicates that they will give distinctive X-ray diffraction patterns.

Primarily X-ray powder diffraction has been used for. Defect and Microstructure Analysis by Diffraction looks at a key aspect of state-of-the-art methods for analyzing the actual structure of materials.

Diffraction analysis is typically based on idealized crystals. The impurities and irregularities that work themselves into virtually all crystal structures, however, cause diffraction peak profiles to broaden and sometimes become asymmetric Cited by:   X-ray powder diffraction was pioneered by Debye & Scherrer () and is now a well established technique that has been used successfully for nearly years.

This is a very important technique for the identification of material phases and their quantitative proportion, microstructure evaluation and molecular structure by: 9.

Thus, when carrying out a powder diffraction measurement it is usual to grind the solid up into fine particles of about 1–10 μm size. These days, rather than use photographic film (figure ) to observe the powder rings, an automatic diffractometer (figure ) is normally used in which a counter is scanned from low to high 2 θ within.

Electron diffraction refers to the wave nature of r, from a technical or practical point of view, it may be regarded as a technique used to study matter by firing electrons at a sample and observing the resulting interference pattern.

This phenomenon is commonly known as wave–particle duality, which states that a particle of matter (in this case the incident electron) can be. Our powder diffractometers typically use the Bragg-Brentano geometry. ωωω 2θ22θθ2θ • The incident angle, ω, is defined between the X-ray source and the sample.

• The diffraction angle, 2θ, is defined between the incident beam and the detector. • The incident angle ω is always ½ of the detector angle 2θ. The indexing of powder diffraction patterns is carried out today by computer programs, and success in this process depends to some extent on the complexity of the structure, and to a very large extent on the accuracy of the primary θ-data.

Defect and Microstructure Analysis by Diffraction is focused on extracting information on the real structure of materials from their diffraction patterns.

The primary features of a powder diffraction pattern are determined by the "idealized" periodic nature of the crystal structure.